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Question:

Orange precipitate in aluminum solution?

So I was trying a home chemistry experiment with sodium hydroxide and aluminum foilI put a bit of sodium hydroxide in a cup, mixed it with water, and reacted some aluminum foil in itIt left a black residue (which I believe to be carbon from the coating on the foil)I left the cup on the windowsill and when I came back a few days later, the black precipitate was orangeThe cup was glass, if that would mean anythingI know that sodium hydroxide can dissolve that sometimes.

Answer:

the black precipitate probably oxidized by sitting in the sun and in the open air2 [Al(OH)4]1- (aluminate ion) forms when Al is placed in NaOH if allowed to sit long enough, the Al(OH)4-1 ion may form with the Na+ in solution to make NaAl(OH)4 as the liquid evaporates.

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