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Question:

Which book in the Old Testament mentioned iron BEFORE iron was invented?

GENESIS 4:22: And Zillah, she also bare Tubal-cain, an instructer of every artificer in brass and iron: and the sister of Tubal-cain was Naamah.

Answer:

Iron invented? God invented iron and that was before Tubal-Cain was invented.
I see. Now, when was iron invented? When was Tubal-cain born? Be precise now, you are the one with the question, therefore we must surmise you have all of the answers.
Waffle Iron The waffle iron was patented on August 24, 1869, invented by Cornelius Swarthout of Troy, New York. The patent (United States #94,xxx) described the invention as a device to bake waffles. IRON, ELECTRIC The electric iron was invented in 1882 by Henry W. Seeley, a New York inventor Seeley patented his electric flatiron on June 6, 1882 (patent no. 259,054). His iron weighed almost 15 pounds and took a long time to warm up. Iron Fe Atomic Number 26 Symbol Fe Atomic Weight 55.847 Discovery Known since prehistoric time. Iron is a relatively abundant element in the universe. The sun and many types of stars contain iron in quantity. Iron is found native in a class of meteorites called siderites and it is a minor constituent of the other two classes of meteorites. The Earth's core is thought to be composed mainly of iron, with about 10% occluded hydrogen. Iron is the fourth most abundant element in the Earth's crust. The most common iron ore is hematite (Fe2O3), from which iron metal is obtained by reduction with carbon. Iron is also found in minerals such as taconite and magnetite, which is commonly seen as black sands along beaches and stream banks.

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