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Question:

A white buildup has formed on stainless steel parts after soaking in NaOH with aluminium pieces How to remove?

The stainless steel tubes have a 5mm internal diameter so i would like to use a chemical to clean them rather than brushing or sandingOriginally i thought the white substance was dried NaOH but HCl or water have not removed itNow i am thinking that it must be some kind of aluminium depositPlease help by identifying what may have formed or even better how to get rid of it

Answer:

Aluminium metal reacts with NaOH to form a number of substancesThe most common is sodium aluminate, but it is also common to form the hydroxide - Al(OH)3This latter product is insoluble in water, but it should dissolve in acidThe choice of acid is a problemIf you are using type 304 stainless steel - or whatever the local equivalent is - do not use HCl because this grade of steel is atttacked by chloride ionsIf you are using type 316 stainless - you do not have a problem in this regardI suggest that you use H2SO4 to be safeYou need quite a concentrated solution of acid - so something like battery acid should be oKGive it time to reactI do not know what you were doing, but mixing NaOH with Al is not advisable, as you have discoveredAlso - unless you have specific training - be careful when dealing with concentrated acidsThey are dangerous.

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