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Try Sock-Ease yarn by Lionbrand Yarn CompanyThey have a web site with free patterns and sell sock making yarn, however, you have to registerRegistration is free and they send you a free newsletter which if you don't want it you can unsubscribe to it They also have free knitting tutorials, I don't think they have one specifically for socks, but they show tutorials for the stitches used in sock makingAs the other poster said, use a light weight yarnHope this helps and good luck with your socks!
There is a superwash merino wool called Zara that I really loveIt's sportweight, which is slightly heavier than most sock yarns, but that means you can also use bigger needlesI made my first socks from a WWI Red Cross patternIf you google Red Cross sock knitting, it's easy to findIt's a very straighforward top-down pattern on size 3 dpn'sIf you use the Zara with this pattern, you'll come out with really great boot socksI also love self-striping wool sock yarn, which you can find just about everywhereI haven't tried Lion Brand Sock-Ease yet, but I've had very good results with other Lion Brand yarns and would definitely suggest it.