i say Spider-Man. He could just pull out Iron Man‘s heart with his webbing.
Plastic is far less expensive, it's lighter, and it doesn't corrode.
Iron man. Spider-man could never catch Iron Man. Iron Man could squash him like a bug.
Peter Parker the amazing Spider-Man vs iron man that's debatable because he webbed up iron man in amazing spider man 544 (but in a what if he hacked his suit). He also got beat up by iron man in a different issue. During the dying wish storyline Dr octopus and spider-man switched minds and Peter Parker dying inspired dr octopus (or SPock if you will) to become a hero the superior spider man He has claws, spider-bots, a backpack with mechanical arms, spider walkers and an army of spiderlings. Earlier dr octopus beat iron man by hacking his suit so SPock wins. By the way the arc reactor is an electro magnet in the comics it's called a RT node
I have seen Spider man beaten Iron man many times in the comic were they both look beat up and bloody. At the end Spider man was always the last one standing. (That was probably Iron Spider man Im not sure) Even Captain America can beat Iron man. If you watch the battle between them in Youtube in this comic called The America Civil War Captain America could have killed Iron man yes killed Iron man. The thing is Iron man isn't really that powerful, the only thing that going for him is his brain, tech, and extremis and that it. I know I didn't give a logical reason and Im sorry but if Spider man and Iron man was to ever fight to the death I will have to go with Spider man.