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Question:

Electrolysis Help Needed Electrodes.?

Yeah, well I was thinking of running a current through water to produce hydrogen gas, harvest it, and try out a little explosion.So.what material should I use for the electrodes? Does it matter? I don‘t have any real electrodes, but I do have paper clips, pencil graphite, iron rods and copper. I do have stainless steel, but this would produce chromium I am pretty sure, and that is dangerous.Basically? Do electrodes only have the effect of changing electrolysis rates? or also their products?

Answer:

Electrodes are likely to corrode, depending on what you dissolve in the water to make it more conductive. A metal as the negative electrode won't corrode because of the electrochemistry there, but the positive electrode attracts the negative ions and discharges them, so Cl- becomes chlorine gas, very corrosive. Or OH- becomes oxygen, likewise. So use graphite as it won't oxidise at temperatures with water around. Pencil graphite is not very conductive: disassemble a spent battery cell and use its carbon electrode. Copper sheets at the positive terminal can develop very colourful oxidations: quite pretty. This is called anodisation. Try bubbling the hydrogen and oxygen into the same container, such as a one gallon plastic container. Discharge FROM A DISTANCE with a spark plug or a fuse wire. Do not use a match! Do not mess about where static electricity might strike a spark.

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